Shakira and Plan B have been booked to perform at the upcoming 2010 MTV Europe Music Awards in Madrid, MTV International said Monday.

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They join the list of performers already announced such as Katy Perry, Kid Rock, Kings of Leon, Linkin Park and Ke$ha. Eva Longoria is to serve as host of the prize presentation.

"This will be my first time in Spain and at the MTV awards," Plan B said in a statement. "Nothing reminds me more of how far I've come in the last six months than opportunities like this."

Slated to be presenters at the Nov. 7 event are "Jersey Shore" cast member Pauly D, actress Emily Osment, "extreme pranksters" The Dudesons and TV personality Johnny Knoxville, the network said.