The song is the first release off Timberlake's forthcoming album, "The 20/20 Experience," due out this year.
The CD will be Timberlake's first since 2006's "FutureSexLoveSounds."
Fans can either exclusively purchase "Suit & Tie" at the iTunes Store or stream the song at the new Myspace at new.myspace.com Monday.
The single will be available for radio play at midnight, RCA Records said.
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